PLATTE CHEMICAL CO., UNITED AGRA PRODUCTS -- CLEAN CROP AMINE 4 2,4-D WEED KILLER -- 6840-00-664-7060 
=====================  Product Identification  =====================

Product ID:CLEAN CROP AMINE 4 2,4-D WEED KILLER
MSDS Date:01/29/1998
FSC:6840
NIIN:00-664-7060
=== Responsible Party ===
Company Name:PLATTE CHEMICAL CO., UNITED AGRA PRODUCTS
Address:150 S. MAIN ST.
City:FREMONT
State:NE
ZIP:68025-5674
Country:US
Info Phone Num:402-727-5100
Emergency Phone Num:402-727-5100
Resp. Party Other MSDS Num.:EPA REGISTRY # 34704-120
CAGE:65551
=== Contractor Identification ===
Company Name:PLATTE CHEMICAL CO., UNITED AGRA PRODUCTS
Address:150 S. MAIN ST.
Box:City:FREMONT
State:NE
ZIP:68025-5674
Country:US
Phone:303-356-4400/INFO 402-727-8222
CAGE:65551

=============  Composition/Information on Ingredients  =============

Ingred Name:2,4-D (DICHLORYLPHENOXYACETIC ACID)  (SARA III)
CAS:94-75-7
RTECS #:AG6825000
Other REC Limits:NONE SPECIFIED
OSHA PEL:10 MG/M3
ACGIH TLV:10 MG/M3; 9192
EPA Rpt Qty:100 LBS
DOT Rpt Qty:100 LBS

Ingred Name:DIMETHYLAMINE  (SARA III)
CAS:124-40-3
RTECS #:IP8750000
Other REC Limits:NONE SPECIFIED
OSHA PEL:5 PPM/STEL15PPM;9293
ACGIH TLV:10 PPM
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS

Ingred Name:2,4-D ACID, DIMETHYLAMINE SALT
CAS:2008-39-1
Other REC Limits:NONE SPECIFIED

Ingred Name:2,4-D ACID (CAS:94-75-7), DIMETHYLAMINE (CAS:124-40-3),
    2,4-D ACID DIMETHYLAMINE SALT (CAS:2008-30-1)
= Wt:46.5
Other REC Limits:SEE EACH INGRED

Ingred Name:INERT INGREDIENTS
= Wt:53.5

=====================  Hazards Identification  =====================

LD50 LC50 Mixture:ORAL LD50 (RAT) IS 1670 MG/KG.
Routes of Entry: Inhalation:YES  Skin:YES  Ingestion:YES
Reports of Carcinogenicity:NTP:NO    IARC:NO	OSHA:NO
Health Hazards Acute and Chronic:ACUTE: MAY BE FATAL IF SWALLOWED OR
    ABSORBED THROUGH SKIN. MAY CAUSE CENTRAL NERVOUS SYSTEM EFFECTS IF
    INHALED OR INGESTED. CHRONIC: LIVER OR KIDNEY DAMAGE OR CENTRAL
    NERVOUS SYSTEM EFFECTS.
Explanation of Carcinogenicity:NONE OF THE INGREDIENTS OF 0.1% OR
    GREATER CONCENTRATION ARE LISTED AS A CARCINOGEN OR SUSPECTED
    CARCINOGEN.
Effects of Overexposure:INHALATION/INGESTION/SKIN: LOSS OF APPETITE,
    NAUSEA, VOMITING, GENERAL TENSENESS, OR MUSCULAR WEAKNESS.
Medical Cond Aggravated by Exposure:PREEXISTING SKIN OR RESPIRATORY
    DISORDERS MAY BE AGGRAVATED BY EXPOSURE TO THIS PRODUCT.

=======================  First Aid Measures  =======================

First Aid:INGESTION: DRINK 1 OR 2 GLASSES OF WATER. DO NOT INDUCE
    VOMITING OR GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. KEEP
    HEAD LOWER THAN CHEST TO AVOID ASPIRATION INTO LUNGS. CALL
    PHYSICIAN IMMEDIATE LY. EYES: FLUSH WITH RUNNING WATER FOR AT LEAST
    15 MIN WHILE HOLDING EYELIDS OPEN TO HELP FLUSH OUT MATERIAL. GET
    MEDICAL ATTENTION. SKIN: REMOVE ALL CONTAMINATED CLOTHING. WASH
    SKIN AND HAIR THOROUGH LY WITH SOAP AND WATER. IF IRRITATION
    PERSISTS, GET MEDICAL ATTENTION. INHALATION: REMOVE TO FRESH AIR.
    IF BREATHING IS DIFFICULT, ADMINISTER OXYGEN; IF BREATHING STOPS
    ADMINISTER ARTIFICIAL RESPIRATI ON. GET MEDICAL ATTENTION
    IMMEDIATELY.

=====================  Fire Fighting Measures  =====================

Extinguishing Media:CONSIDERED NON-CUMBUSTIBLE; USE MEDIUM APPROPRIATE
    TO SURROUNDING FIRE. DRY CHEMICAL, CO2, FOAM, WATER SPRAY OR FOG.
Fire Fighting Procedures:SMOKE AND FUMES FROM FIRE MAY CONTAIN
    HAZARDOUS COMPONENTS. WEAR SELF-CONTAINED BREATHING APPARATUS AND
    FULL PROTECTIVE CLOTHING. FIGHT FIRE FROM UPWIND SIDE. AVOID
    RUN-OFF. KEEP NON-ESSENTIAL PERSONN EL AWAY FROM IMMEDIATE FIRE
    AREA, AND OUT OF ANY FALL-OUT OR RUN-OFF AREAS.
Unusual Fire/Explosion Hazard:IF WATER IS USED TO FIGHT FIRE OR COOL
    CONTAINERS, CONTAIN RUN-OFF BY DIKING TO PREVENT CONTAMINATION OF
    WATER SUPPLIES

==================  Accidental Release Measures  ==================

Spill Release Procedures:CONTAIN SPILL; ABSORB LIQUIDS BY COVERING WITH
    CLAY OR OTHER ABSORBENT MATERIAL; VACUUM, SCOOP OR SWEEP UP WASTES
    AND PLACE IN CONTAINER FOR DISPOSAL. WASH SPILL AREA WITH WATER
    CONTAINING STRONG DETE RGENT, ABSORB AND SWEEP UP (AS ABOVE) AND
    PLACE IN A CONTAINER FOR DISPOSAL. REPEAT PROCEDURE AS NEEDED
    UNTIOL AREA IS CLEAN.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

======================	Handling and Storage  ======================

Handling and Storage Precautions:DO NOT STORE BELOW 25F. IF FROZEN,
    WARM TO 70F AND REDISSOLVE BEFORE USING BY ROLLING OR SHAKING THE
    CONTAINER.	STORE IN A SAFE MANNER. STORE IN ORIGINAL CONTAINER
    ONLY. STORE IN COOL, DRY PLACE. KEE P CONTAINER TIGHTLY CLOSED WHEN
    NOT IN USE.
Other Precautions:DO NOT CONTAMINATE WATER SUPPLIES BY HANDLING OR
    STORAGE OF PRODUCT, CLEANING OF EQUIPMENT OR DISPOSAL OF WASTES.
    KEEP WORK AND STORAGE AREAS CLEAN. IMMEDIATELY CLEAN UP ANY SPILLS
    WHICH OCCUR DURING	HANDLING AND STORAGE.

=============  Exposure Controls/Personal Protection  =============

Respiratory Protection:TO AVOID BREATHING SPRAY OR MISTS, WEAR AN
    NIOSH-APPROVED PESTICIDE RESPIRATOR.
Ventilation:USE LOCAL EXHAUST IN CONFINED AREAS; USE ADEQUATE
    MECHANICAL VENTILATION IN OTHER AREAS.
Protective Gloves:RUBBER GLOVES; CHEMICAL RESISTANT GLOVES
Eye Protection:CHEMICAL SAFETY GLASSES OR GOGGLES.
Other Protective Equipment:WEAR LONG-SLEEVED SHIRT AND LONG PANTS,
    SHOES PLUS SOCKS.
Work Hygienic Practices:DO NOT STORE FOOD, BEVERAGES, OR TOBACCO
    PRODUCTS IN THE STORAGE AREA. PREVENT EATING, DRINKING, TOBACCO
    USAGE. ALWAYS WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
FOLLOW MANUFACTURER'S INSTRUCTIONS FOR CLEANING AND MAINTAINING PPE. IF
    NO SUCH INSTRUCTIONS FOR WASHABLES, USE DETERGENT AND HOT WATER.
    KEEP AND WASH PPE SEPARATELY FROM OTHER LAUNDRY.

==================  Physical/Chemical Properties  ==================

HCC:V7
Boiling Pt:=100.C, 212.F
Vapor Pres:20.7
Vapor Density:0.021
Spec Gravity:1.158-1.168
pH:7.5-9.0
Viscosity:11.5-13.0 CENTIPOISE
Evaporation Rate & Reference:< BUTYL ACETATE
Solubility in Water:MISCIBLE
Appearance and Odor:AMBER TO NEARLY BLACK LIQUID WITH "FISHY"
    AMINE-LIKE ODOR.
Percent Volatiles by Volume:APPROX 50%

=================  Stability and Reactivity Data  =================

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS, ACIDS.
Stability Condition to Avoid:EXCESSIVE HEAT.
Hazardous Decomposition Products:AMMONIA, OXIDES OF NITROGEN,
    CHLORINE-CONTAINING COMPOUNDS AND OTHER UNKNOWN HAZARDOUS
    MATERIALS. INCOMPLETE COMBUSTION MAY LEAD TO FORMATION OF CARBON
    MONOXIDE AND/OR OTHER ASPHYXIANTS.

===================  Toxicological Information	===================

Toxicological Information:ACUTE ORAL LD50 (RAT) = 1670 MG/KG; ACUTE
    DERMAL LD50 (RABBIT) > 2000 MG/KG; ACUTE INHALATION LC50 (RAT) >
    5.28 MG/KG.

=====================  Ecological Information  =====================

Ecological:TOXIC TO AQUATIC INVERTEBRATES.

====================  Disposal Considerations  ====================

Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND
    FEDERAL REGULATIONS.

=====================  Regulatory Information  =====================

SARA Title III Information:SARA TITLE III HAZARD CATEGORY: IMMEDIATE=
    YES, DELAYED= NO, FIRE, REACTIVE AND SUDDEN RELEASE OF PRESSURE =
    NO. SUBSTANCES REGULATED UNDER SARA TITLE SEC 313: 2,4-D (CAS
    94-75-7) = 38.6%

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